443791-86-4

Upstream product

• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 443791-96-6 (1S,2S,3S,3aR,4R,5S,7aS)-3-(4-Bromo-benzoyloxy)-5-(tert-butyl-dimethyl-silanyloxymethyl)-2,6-dimethyl-1-triisopropylsilanyloxy-2,3,3a,4,5,7a-hexahydro-1H-indene-4-carboxylic acid methyl ester 
• 443791-89-7 Benzoic acid (4E,6E)-(1R,2S,3S)-8-(tert-butyl-dimethyl-silanyloxy)-1-((E)-2-methoxycarbonyl-vinyl)-2,6-dimethyl-3-triisopropylsilanyloxy-octa-4,6-dienyl ester 
• 443791-97-7 4-Bromo-benzoic acid (3aS,5aS,6S,7R,8S,8aR,8bR)-6-hydroxy-4,7-dimethyl-1-oxo-3,3a,5a,6,7,8,8a,8b-octahydro-1H-indeno[4,5-c]furan-8-yl ester 

Relevant academic research and scientific papers

Synthetic studies on FR182877: An asymmetric synthesis of the AB ring moiety of FR182877 via a diastereoselective intramolecular Diels-Alder reaction

An asymmetric synthesis of the AB ring moiety of FR182877, possessing seven asymmetric centers, via a diastereoselective IMDA reaction is described.