443889-39-2Relevant academic research and scientific papers
SYNTHESES OF AMINOCYCLITOLS AND AMINOCYCLITOL-OLIGOGLYCOSIDES FROM URONIC ACIDS AND GLUCURONIDE-SAPONINS BY MEANS OF AN ELECTROLYTIC DECARBOXYLATION REACTION
Kitagawa, Isao,Kamigauchi, Toshiyuki,Shirakawa, Kiyoharu,Ikeda, Yoshiharu,Ohmori, Hidenobu,Yoshikawa, Masayuki
, p. 349 - 354 (2007/10/02)
By use of the electrolytic decarboxylation reaction as the key step, aminocyclitols (6b, 7b, 8b, 10b, 14b) and aminocyclitol-oligoglycosides (e.g. 18) have been conveniently synthesized from uronic acids (1, 9, 12) and glucuronide-saponins (e.g. 15).The conversions include the first syntheses of optically active D-neo- and L-neo-nitrocyclitols (10, 14).
