444809-27-2

Upstream product

• 444809-19-2 (1R)-2-bromo-3-methoxymethoxymethyl-4,4-dimethyl-cyclohex-2-enyloxy-tert-butyl-dimethyl-silane 
• 6553-64-6 6,6-Dimethyl-2-cyclohexen-1-one 
• 444809-15-8 1-methoxymethoxymethyl-6,6-dimethyl-cyclohex-2-enol 
• 444809-16-9 3-methoxymethoxymethyl-4,4-dimethyl-cyclohex-2-enone 
• 444809-18-1 (1R)-2-bromo-3-methoxymethoxymethyl-4,4-dimethyl-cyclohex-2-enol 
• 444809-17-0 2-bromo-3-methoxymethoxymethyl-4,4-dimethyl-cyclohex-2-enone 

Downstream Products

• 444809-20-5 (1R)-[2-bromo-3-(3,4-dimethoxy-benzyloxymethyl)-4,4-dimethyl-cyclohex-2-enyloxy]-tert-butyl-dimethyl-silane 
• 444809-23-8 ((2S,3R)-3-Benzyloxymethyl-3-methyl-oxiranyl)-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-2-(3,4-dimethoxy-benzyloxymethyl)-3,3-dimethyl-cyclohex-1-enyl]-methanone 
• 444809-22-7 ((2R,3R)-3-Benzyloxymethyl-3-methyl-oxiranyl)-[(R)-6-(tert-butyl-dimethyl-silanyloxy)-2-(3,4-dimethoxy-benzyloxymethyl)-3,3-dimethyl-cyclohex-1-enyl]-methanol 
• 1027739-76-9 ((2S,3R)-3-Benzyloxymethyl-3-methyl-oxiranyl)-[(R)-2-(3,4-dimethoxy-benzyloxymethyl)-6-hydroxy-3,3-dimethyl-cyclohex-1-enyl]-methanone 
• 444809-24-9 (2S,3S,8aR)-2-Benzyloxymethyl-5-(3,4-dimethoxy-benzyloxymethyl)-3-hydroxy-2,6,6-trimethyl-2,3,6,7,8,8a-hexahydro-chromen-4-one 
• 444809-25-0 (2S,3S,3aS,8aR)-2-Benzyloxymethyl-2,6,6-trimethyl-2,3,6,7,8,8a-hexahydro-5H-furo[2,3,4-de]chromene-3,3a-diol 

Relevant academic research and scientific papers

Convergent enantioselective synthesis of the tricyclic core of phomactin A

(Matrix Presented) The tricyclic core of phomactin A was synthesized from 6,6-dimethyl-2-cyclohexen-1-one. Key reactions include the addition of a cyclohexenyllithium reagent to an epoxyaldehyde and a regioselective intramolecular epoxide opening to insta