445042-73-9Relevant academic research and scientific papers
Alkynethiolate ligands in the syntheses of iron carbonyl derivatives. Crystal structure of [(η5-C5H5 Fe(CO)2(SC≡CSiMe3)]
Delgado, Esther,Donnadieu, Bruno,García, Silvia,Zamora, Félix
, p. 21 - 24 (2007/10/03)
The complexes [η5-C5H5)Fe(CO)2(SC≡CR)] (R = Bu, SiMe3) have been obtained by reaction of [(η5-C5H5)Fe(CO)2I] and the corresponding LiSC≡CR. These are the first examples of mononuclear iron compounds containing alkynethiolate ligands. The crystal structure of [(η5-C5H5)Fe(CO)2(SC≡CSiMe3)] has been determined by X-ray diffraction. The role of [(η5-C5H5)Fe(CO)2(SC≡CSiMe3)] as a metalloligand in its reactions with metal carbonyls has been explored.
