445412-15-7Relevant academic research and scientific papers
Stereospecific construction of three contiguous quaternary carbon atoms. Synthesis of (±)-3-methoxythaps-8-ene
Srikrishna,Ramachary
, p. 2765 - 2768 (2002)
Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary carbon atoms, employing a combination of a Claisen rearrangement and an intramolecular diazoketone cyclopropanation as key reactions, is described.
Total synthesis of (±)-β-microbiotene, (±)-microbiotol, (±)-cyclocuparanol and (±)-β-cuparenones
Srikrishna,Ramachary
, p. 805 - 817 (2008/09/18)
Total synthesis of (±)-β-microbiotene, (±)-microbiotol, (±)-cyclocuparanol and their epimers along with (±)-β- cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the gener
Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenones
Srikrishna,Ramachary
, p. 1216 - 1226 (2007/10/03)
Total synthesis of (±)-grimaldone, epigrimaldone and α-cuparenone has been described. A combination of orthoester Claisen rearrangement, an acid catalysed rearrangement of a diazoketone for the generation of bicyclo[4.2.1]nonanedione, a retro-Claisen cond
Approaches to sesquiterpenes containing three contiguous quaternary carbon atoms. Synthesis of 3-methoxythapsene
Srikrishna,Ramachary
, p. 751 - 761 (2007/10/03)
Synthetic approach to 3-alkoxythapsane, comprising of the carbon framework of a small group of sesquiterpenes containing three contiguous quaternary carbon atoms has been described. A combination of alkylation, orthoester Claisen rearrangement and intramo
