445424-02-2Relevant academic research and scientific papers
Regio- and Stereoselective Cyanotriflation of Alkynes Using Aryl(cyano)iodonium Triflates
Wang, Xi,Studer, Armido
supporting information, p. 2977 - 2980 (2016/03/19)
A novel, mild, and versatile approach for regioselective syn-addition of both the CN and OTf groups of aryl(cyano)iodonium triflates to alkynes is described. The reaction uses Fe-catalysis and can be conducted in gram scale. Products of the vicinal cyanotriflation can be stereospecifically readily further functionalized, rendering the method highly valuable.
Highly flexible synthesis of 2-arylethylamine derivatives
Siebeneicher, Holger,Doye, Sven
, p. 1213 - 1220 (2007/10/03)
A new and highly flexible procedure for the synthesis of 2-arylethylamine derivatives is described. By the new procedure, the target compounds can be synthesized with high diversity in three steps from aryl halides, terminal alkynes, and primary amines. T
