445482-88-2Relevant academic research and scientific papers
Chiral phosphinooxathiane ligands for catalytic asymmetric Diels-Alder reaction
Nakano, Hiroto,Suzuki, Yuichiro,Kabuto, Chizuko,Fujita, Reiko,Hongo, Hiroshi
, p. 5011 - 5014 (2002)
Chiral cationic palladium-phosphinooxathiane complexes have been found to be effective catalysts for enantioselective Diels-Alder (DA) reaction of cyclopentadiene with acyl-1,3-oxazolidin-2-ones to give the corresponding DA adducts in good yield and high enantioselectivity up to 93% ee.
