446036-14-2Relevant academic research and scientific papers
Pyridine Wingtip in [Pd(Py-tzNHC)2]2+ Complex Is a Proton Shuttle in the Catalytic Hydroamination of Alkynes
Virant, Miha,Mihela?, Mateja,Gazvoda, Martin,Cotman, Andrej E.,Frantar, Anja,Pinter, Balazs,Ko?mrlj, Janez
, p. 2157 - 2161 (2020)
The cationic palladium(II) complex 1 of pyridyl-mesoionic carbene ligand catalyzes Markovnikov-selective intermolecular hydroamination between anilines and terminal alkynes into the corresponding imines. The reaction proceeds at room temperature, in the a
Commercial Supported Gold Nanoparticles Catalyzed Alkyne Hydroamination and Indole Synthesis
Liang, Shengzong,Hammond, Luisa,Xu, Bo,Hammond, Gerald B.
supporting information, p. 3313 - 3318 (2016/10/21)
Commercial gold nanoparticles supported on titanium dioxide (TiO2) were found to be a highly efficient catalyst for alkyne hydroamination. Terminal alkynes could easily undergo intermolecular hydroamination with low catalyst loadings (0.2 mol% Au) under solvent-free conditions. Indoles were efficiently synthesized using microwave heating through intramolecular hydroamination. (Figure presented.).
Addition of alkynes to a gallium bis-amido complex: Imitation of transition-metal-based catalytic systems
Fedushkin, Igor L.,Nikipelov, Alexander S.,Morozov, Alexander G.,Skatova, Alexandra A.,Cherkasov, Anton V.,Abakumov, Gleb A.
supporting information; experimental part, p. 255 - 266 (2012/02/16)
Acetylene, phenylacetylene, and alkylbutynoates add reversibly to (dpp-bian)Ga-Ga(dpp-bian) (dpp-bian=1,2-bis[(2,6-diisopropylphenyl)-imino] acenaphthene) to give addition products [dpp-bian(R1C=CR 2)]Ga-Ga[(R2C=CR1/
