446293-91-0Relevant articles and documents
Reusable Nickel Nanoparticles-Catalyzed Reductive Amination for Selective Synthesis of Primary Amines
Murugesan, Kathiravan,Beller, Matthias,Jagadeesh, Rajenahally V.
supporting information, p. 5064 - 5068 (2019/03/19)
The preparation of nickel nanoparticles as efficient reductive amination catalysts by pyrolysis of in situ generated Ni-tartaric acid complex on silica is presented. The resulting stable and reusable Ni-nanocatalyst enables the synthesis of functionalized and structurally diverse primary benzylic, heterocyclic and aliphatic amines starting from inexpensive and readily available carbonyl compounds and ammonia in presence of molecular hydrogen. Applying this Ni-based amination protocol, -NH2 moiety can be introduced in structurally complex compounds, for example, steroid derivatives and pharmaceuticals.
PEST ATTRACTANT COMPOSITIONS COMPRISING THEASPIRANE
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Page/Page column 28; 29; 30, (2018/08/26)
Described herein is a pest attractant composition comprising theaspirane or an attractive derivative, homologue, isomer or mixture of isomers thereof. Also described is use of the composition for attracting pests and a trap for catching pests comprising t
Molecularly Defined Manganese Pincer Complexes for Selective Transfer Hydrogenation of Ketones
Perez, Marc,Elangovan, Saravanakumar,Spannenberg, Anke,Junge, Kathrin,Beller, Matthias
, p. 83 - 86 (2017/01/17)
For the first time an easily accessible and well-defined manganese N,N,N-pincer complex catalyzes the transfer hydrogenation of a broad range of ketones with good to excellent yields. This cheap earth abundant-metal based catalyst provides access to useful secondary alcohols without the need of hydrogen gas. Preliminary investigations to explore the mechanism of this transformation are also reported.