447397-76-4Relevant academic research and scientific papers
First successful reaction of a silyl anion with hafnium tetrachloride
Frank, Dieter,Baumgartner, Judith,Marschner, Christoph
, p. 1190 - 1191 (2002)
Hafnium tetrachloride reacts with the tris(trimethylsilyl)silyl potassium tmen adduct (1) to form a [tris(trimethylsilyl)silyl]trichlorohafnium tmen complex (2); reaction of 2 with 2,6-dimethylphenylisonitrile leads to insertion into the silicon hafnium bond (4).
