447413-03-8

Basic information

• Product Name: 2-hydroxy-N-[2-(methylsulfanyl)phenyl]benzamide
• Synonyms: 2-hydroxy-N-[2-(methylsulfanyl)phenyl]benzamide;2-hydroxy-N-[2-(methylthio)phenyl]benzamide;MFCD02934416
• CAS NO: 447413-03-8
• Molecular Formula: C₁₄H₁₃NO₂S
• Molecular Weight: 259.33
• Mol File: 447413-03-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-hydroxy-N-[2-(methylsulfanyl)phenyl]benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-N-[2-(methylsulfanyl)phenyl]benzamide(447413-03-8)
• EPA Substance Registry System: 2-hydroxy-N-[2-(methylsulfanyl)phenyl]benzamide(447413-03-8)

Safety Data

• Hazardous Substances Data: 447413-03-8(Hazardous Substances Data)

Upstream product

• 51942-32-6 2-(benzoylamino)-1-(methylthio)benzene 

Relevant articles and documents

Copper-mediated hydroxylation of arenes and heteroarenes directed by a removable bidentate auxiliary

A copper-mediated C-H hydroxylation of arenes and heteroarenes using our newly developed PIP directing group has been developed. This procedure is scalable and compatible with a wide range of functional groups and heteroarenes, providing an operationally simple protocol for the synthesis of o-hydroxybenzamides. The hydroxylation of nicotinamides gave 4-oxo-1,4-dihydropyridine-3-carboxamides selectively. Preliminary mechanistic studies implicate that a basic ligand-enabled, irreversible, rate-determining CMD step is most likely involved in this process.