4485-12-5 Usage
Chemical Properties
Lithium stearate is a white powder. slightly soluble in water and ethanol, with a solubility of 0.09 g/100ml in water and 0.04 g/100ml in ethanol. insoluble in ethyl acetate and mineral oil. It forms colloids in mineral oil. It is decomposed into stearic acid and the corresponding lithium salt when encountering strong acid.
Uses
Lithium stearate is used as a thickener and gelling agent to prepare oils into lubricating greases. It is the active component of lithium grease. Further, it is used as lubricants, lubricant additives, plastic and rubber products. In addition to this, it is used as a stabilizing agent in the plastics industry.
Application
Lithium stearate is a lithium salt of stearic acid (LiC18H35O2) and is used as a processing aid or lubricant during filled elastomer part production. it is used as general purpose lubricating greases providing high resistance to water and the useful at both high and low temperature, which have found extensive applications in the automotive, aircraft and heavy machinery industry. Lithium stearate is the preferred lubricant because of its cleansing and scavenging action during sintering.
Preparation
Lithium Stearate is prepared by the reaction of lithium hydroxide with stearic acid (cooking tallow or other animal fat).Synthesis Step: Dissolve 10 g of stearic acid in 100 mL of 95% ethanol, titrate with 0.5 mol/L lithium hydroxide ethanol solution, and use phenolphthalein as an indicator. After the reaction reaches the equivalence point, the precipitated lithium stearate soap is filtered out. The crude product can be recrystallized with 95% ethanol to obtain pure product.
Safety Profile
Low toxicity by
ingestion. Warning: This substance is
spontaneously combustible. When heated to
decomposition it emits toxic vapors of
lithum.
Check Digit Verification of cas no
The CAS Registry Mumber 4485-12-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,4,8 and 5 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 4485-12:
(6*4)+(5*4)+(4*8)+(3*5)+(2*1)+(1*2)=95
95 % 10 = 5
So 4485-12-5 is a valid CAS Registry Number.
InChI:InChI=1/C18H36O2.Li/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17-18(19)20;/h2-17H2,1H3,(H,19,20);/q;+1/p-1
4485-12-5Relevant articles and documents
Cation-controlled crystal growth of silver stearate: Cryo-TEM investigation of lithium vs sodium stearate
Dong, Jingshan,McCormick, Alon V.,Davis, H. Ted,Whitcomb, David R.
experimental part, p. 2263 - 2267 (2010/11/18)
Cryo-TEM, SAXS, and light microscopy techniques were used to probe the morphology and kinetics of silver stearate self-assembly and crystallization from the reaction of silver nitrate with lithium stearate. Unlike the reaction of sodium stearate with silver nitrate, which proceeds via micelle aggregation, the lithium stearate forms vesicles that drastically change the reaction kinetics of the silver stearate nucleation and self-assembly process. In addition, even with excess silver nitrate present, only about 80% of the lithium stearate can be converted to silver stearate. The presence of the residual lithium stearate inhibits the silver stearate crystal growth process. Consequently, no silver stearate micelle aggregates of any significant size form, unlike the system utilizing sodium stearate. Instead, significantly smaller silver stearate crystals result from lithium stearate compared to the silver stearate crystals from sodium stearate and provide an opportunity to further control silver stearate self-assembly and crystal growth.
