449793-55-9Relevant academic research and scientific papers
Synthesis of 2-(2-R1)-hydrazino)-5-(R2-benzyl)-2- thiazolines on the basis of meerweins arylation products of allyl isothiocyanate
Karpyak, Volodymyr V.,Obushak, Mykola D.,Ganushchak, Mykola I.
, p. 263 - 268 (2007/10/03)
3-Aryl-2-chloropropylisothiocyanates (1) are formed by interaction of arene-diazonium chlorides with allyl isothiocyanate. Adducts 1 react with monoacylhydrazines to form 1-acyl-4-(3-aryl-2-chloropropyl)thiosemicarbazides (2a-d). Thiosemicarbazides 2a-d in the presence of bases selectively transform into 2-(2-R1-hydrazino)-5-(R2-benzyl)-2-thiazolines (3a-d).
