449797-98-2

Upstream product

• 7348-78-9 (Z)-1-bromo-2-pentene 
• 2325-10-2 (S,S)-hydrobenzoin 

Downstream Products

• 449797-99-3 (2S,3S,5R)-2,3-Diphenyl-5-((E)-propenyl)-[1,4]dioxane 
• 449798-04-3 (4S,5S)-5-((2S,5S,6S)-5,6-Diphenyl-[1,4]dioxan-2-yl)-2-trichloromethyl-4,5-dihydro-oxazole-4-carboxylic acid 

Relevant academic research and scientific papers

Synthesis of (+)-polyoxamic acid and D-sorbitol from simple achiral allylic halides emploing (S,S)-hydrobenzoin as a chiral source

Coupling of cis-1-bromo-2-pentene and (S,S)-hydrobenzoin stannylene acetal followed by regio- and stereoselective transformations of the resulting allylic ether gave (+)-polyoxamic acid and a similar procedure was applied to the synthesis of D-sorbitol from trans-1-iodo-2-hexene.