451503-08-5Relevant academic research and scientific papers
Oxidatively generated electrophiles as initiators of epoxide cascade cyclization processes
Kumar, V. Satish,Wan, Shuangyi,Aubele, Danielle L.,Floreancig, Paul E.
, p. 3570 - 3578 (2007/10/03)
Oxidatively generated oxocarbenium ions are shown to be effective promoters of polyepoxide cascade cyclization reactions to form polyether compounds. The reaction conditions are neutral, ensuring that background acid-mediated processes are not operative a
Electron transfer initiated heterogenerative cascade cyclizations: Polyether synthesis under nonacidic conditions
Kumar, V. Satish,Aubele, Danielle L.,Floreancig, Paul E.
, p. 2489 - 2492 (2007/10/03)
(Matrix presented) Single-electron oxidation has been employed to initiate heterogenerative cascade cyclization reactions that form polyether compounds under essentially neutral conditions. The reactions proceed through mesolytic benzylic carbon-carbon bo
