452085-65-3

Upstream product

• 452085-64-2 (E)-4,6-Dimethyl-16-phenyl-hexadec-5-ene-1,4-diol 
• 452085-63-1 (E)-4,6-Dimethyl-16-phenyl-hexadeca-1,5-dien-4-ol 
• 452085-62-0 (E)-4-Methyl-14-phenyl-tetradec-3-en-2-one 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 85562-26-1 [4-(6-Bromohexyl)butyl]benzene 
• 10556-93-1 4-methoxypent-3-en-2-one 
• 452085-70-0 1-(tert-butyl-dimethyl-silanyloxy)-4,6-dimethyl-16-phenyl-hexadec-5-en-4-ol 

Relevant academic research and scientific papers

First total synthesis of natural 6-epiplakortolide e.

[reaction: see text] Natural 6-epiplakortolide E was first synthesized from readily available 1-bromo-10-phenyldecane in 10 steps by using singlet oxygen-mediated Diels-Alder reaction to form cyclic peroxide followed by a directed iodolactonization to give the peroxylactone core.