452096-44-5Relevant academic research and scientific papers
Manganese(III) Acetylacetonate-Mediated Phosphorylation of Enamides at Room Temperature
Liu, Yue,Liu, Zhanxiang,Zhang, Yuhong,Xiong, Chunhua
supporting information, p. 3492 - 3496 (2018/09/14)
A highly Z-selective phosphorylation by Manganese(III) acetylacetonate-mediated cross-dehydrogenative-coupling of enamides and phosphine oxides has been developed under mild conditions. The reaction shows broad substrate scope and functional group compatibility. DFT studies revealed that the formation of Z-products is presumably due to the presence of an intramolecular hydrogen bond. β-Aminophosphine could be readily obtained by reduction and hydrolysis of the product. (Figure presented.).
Synthesis, X-ray crystal structures and Horner-Wittig addition reactions of some protected β-aminophosphine oxides
Feeder, Neil,Fox, David J.,Medlock, Jonathan A.,Warren, Stuart
, p. 1175 - 1180 (2007/10/03)
Several protected β-aminophosphine oxides have been synthesised and investigated in the Horner-Wittig addition reaction. Crystal structures of an enantiomerically pure β-amino phosphine oxide and a Horner-Wittig addition product are presented. Horner-Witt
