4533-93-1Relevant academic research and scientific papers
Phase transfer catalysis in synthesis of organylthio(organyltelluro) acetylenes
Martynov, Alexander V.,Mirskova, Anna N.,Le Guillanton, Georges
, p. 245 - 250 (2007/10/03)
Phase transfer reaction of diorganyl ditellurides with organyl-2,2-dichlorovinyl sulfides, using as phase transfer catalysts benzyltriethylammonium chloride or 18-crown-6 ether, was used as a new general method to prepare organylthio(organyltelluro)acetylenes R-S-C≡C-Te-R′. The organyltellurolate anion formed in the presence of NaOH is the reaction intermediate.
DARSTELLUNG UND REAKTIONEN VON TRIPHENYLPHOSPHORANEN
Bestmann, Hans Juergen,Roth, Kurt
, p. 1681 - 1684 (2007/10/02)
Starting from triphenylphosphoranes 9 1.1-bis (alkylthio) allenes 1, 1.1-bis(alkylthio)butatrienes 3, bis(alkylthio)acetylenes 17 and tris(alkylthio)ethylenes 18 are available.
