4535-95-9Relevant academic research and scientific papers
New Synthetic Methods for Seven- and Eight-Membered Cyclic Ethers Based on the Ring-Expansion Reactions of Hydroxy or Lithioxy Methoxyallenylisochroman Derivatives
Nagao, Yoshimitsu,Tanaka, Satoru,Hayashi, Kazuhiko,Sano, Shigeki,Shiro, Motoo
, p. 481 - 484 (2007/10/03)
The Pd(0)-catalyzed ring-expansion reactions of hydroxy methoxyallenyl-4,4-dialkylisochroman derivatives in the presence of P(o-tolyl)3 proceeded smoothly via hydropalladation to give 3-benzoxepan-1-one derivatives in high yields. Treatment of
Chromium trioxide oxidation products from 4-spiro-1-phenylisochromans
Gatta,Settimj
, p. 1267 - 1270 (2007/10/02)
Chromium trioxide oxidation of 1-phenylisochroman-4-spiro-1'-cyclopentane (1a) in acetic acid led to the expected 1-(2-benzoylphenyl)cyclopentanecarboxylic acid (IIa), while its 6,7-dimethoxy analogue Ib and 6,7-dimethoxy-1-phenylisochroman-4-spiro-4'-(1'
