4547-77-7

Upstream product

• 6738-06-3 phenylethynylmagnesium bromide 
• 13146-23-1 copper(I) phenylacetylenide 
• 536-74-3 phenylacetylene 
• 33440-88-9 silver phenylacetylide 
• 7719-12-2 phosphorus trichloride 
• 3126-13-4 Tri-n-propylphenylethinyl-stannan 

Downstream Products

• 16787-38-5 Ni(CO)2(C₂₄H₁₅P)2 
• 125914-28-5 ((phenylethinyl)2phosphane((η2-ethinylphenyl)(carbonyl)5dicobalt))2 
• 129264-01-3 ((η2-CC-Ph)Co2(CO)5)2(P(η2-CCPh)Co2(CO)6(CCPh))2 
• 100676-92-4 tetrakis[tri(phenylethynyl)phosphine]platinum⁽⁰⁾ 
• 86155-88-6 tetrakis[tri(phenylethynyl)phosphine]palladium⁽⁰⁾ 
• 87635-16-3 NiCO(P(C₂C₆H₅)3)3 
• 87635-18-5 Ni(P(C₂C₆H₅)3)4 
• 83136-71-4 [Cr(CO)5(P(C₂C₆H₅)3)] 
• 91946-78-0 cis-[chrom-tetracarbonyl-(P(C₂Ph)3)2] 
• 91946-74-6 cis-[W-tetracarbonyl-(P(C₂Ph)3)2] 
• 83152-07-2 [W(CO)5(P(C₂C₆H₅)3)] 
• 473916-06-2 (tris(phenylacetylenyl)phosphine)Ru(II)(CO)(5,15-bis(3',5'-di-tert-butyl)phenyl-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphyrin) 
• 172331-63-4 ([(PhC.tplbond.C)3P]Ag(I)(μ-OSO2CF3))2 

Relevant academic research and scientific papers

Reactions of (Me2C)(Me2Si)[(η5-C 5H3)Mo(CO)3]2 with phosphanylalkynes: Rearrangement of phosphanylalkynes into phosphido-substituted vinylidenyl ligands by cleavage of the P-C(al

This article deals with the thermal reactions of the doubly bridged bis(cyclopentadienyl) dinuclear molybdenum complex (Me2C)(Me 2Si)[(η5-C5H3)Mo(CO) 3]2 (1) with a series of pho

New Approach to Phosphinoalkynes Based on Pd- and Ni-Catalyzed Cross-Coupling of Terminal Alkynes with Chlorophosphanes

(Equation presented) The first example of direct phosphination of terminal alkynes with chlorophosphanes catalyzed by Ni or Pd complexes is described. Both aromatic and aliphatic terminal acetylenes undergo the coupling reaction to give corresponding coup

A Convenient and Direct Route to Phosphinoalkynes via Copper-Catalyzed Cross-Coupling of Terminal Alkynes with Chlorophosphanes

A new efficient method to obtain various alkynylphosphanes R nP(≡R′)3-n [R = Ar, Alk, alkoxy, amido R′ = Ar, Het, Alk, CH2Z (Z = OMe, NMe2), n = 0-2] has been developed by means of cross-coupling reaction of chl

Zum Koordinationsverhalten von Tris-phenylethinyl-phosphan; Synthese und Charakterisierung von ((H5C6CC)2P2-CCC6H5)Co2(CO)5>)2

The reaction of P(CCC6H5)3 (I) with Co2(CO)8 (II) yields ((H5C6CC)2P2-CCC6H5)Co2(CO)5>)2 (III) a compound containing a six-membered C2P2Co2 ring.One of the three alkyne units of I in III is coordinated side-on to the two cobalt atoms of one

CC Stretching Frequencies and δ31P Values of Phosphanes P(CCC6H5)n(C6H5)3-n

The νCC frequencies and the chemical shifts δ31P of the title compounds are reported and discussed.The δ31P values depend on the number n of the phenylethynyl groups (n = 3,2,1,0) according to the equation δ31P = -(27.60 * n +5.72).The shielding of the