45481-27-4Relevant academic research and scientific papers
Redistribution Reactions Involving Lithium Aluminium Hydride and Lithium Tetraphenylaluminate
Ashby, E. C.,Goel, A. B.
, p. 134 - 138 (2007/10/02)
Redistribution reactions involving LiAlH4 and LiAlPh4 were performed by mixing the reagents in appropriate ratios.The products: LiAlH3Ph, LiAlH2Ph2 and LiAlHPh3 were isolated and characterised by elemental analysis, infrared and nmr spectroscopy and DTA-TGA analysis.These products were also prepared by the reaction of PhLi with AlHnPh3-n (where n=1-3) in diethylether.Also PhAlH2 and Ph2AlH were prepared by the reaction of Ph3Al and AlH3 in both diethyl ether and THF in the appropriate stoichiometric ratios.
