455260-37-4Relevant academic research and scientific papers
Synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3(+) cations via addition of nucleophiles to (oxocyclohexadienyl)Mn(CO)3 in the presence of chiral ligands
Son, Seung Uk,Park, Kang Hyun,Lee, Seung Jung,Seo, Hwimin,Chung, Young Keun
, p. 1230 - 1231 (2007/10/03)
The first example of the synthesis of planar chiral (1,3-disubstituted arene)Mn(CO)3(+) cations (3) has been demonstrated by a reaction of (p-cresol)Mn(CO)3(+) with KOBu-t followed by adition of nucleophiles and subsequent quenching with electrophiles in the presence of (S)-binaphthol in CH2Cl2.
Studies on the chemistry of manganese tricarbonyl cations of phenol and cresols
Seo, Hwimin,Lee, Si-Geun,Shin, Dong Mok,Hong, Bog Ki,Hwang, Sungu,Chung, Doo Soo,Chung, Young Keun
, p. 3417 - 3425 (2008/10/08)
Treatment of (arene)tricarbonylmanganese cations (arene = phenol, cresol) with nucleophiles affords η5-cyclohexadienyl complexes that can be demetalated to give ortho-substituted phenols. Acylation of the phenolic oxygen in the η5-cy
