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455331-05-2

2-(dimethylphenylsilyl)ethoxymethyl chloride is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 455331-05-2 Structure

  • Basic information

    1. Product Name: 2-(dimethylphenylsilyl)ethoxymethyl chloride
    2. Synonyms:
    3. CAS NO:455331-05-2
    4. Molecular Formula:
    5. Molecular Weight: 228.794
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 455331-05-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-(dimethylphenylsilyl)ethoxymethyl chloride(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-(dimethylphenylsilyl)ethoxymethyl chloride(455331-05-2)
    11. EPA Substance Registry System: 2-(dimethylphenylsilyl)ethoxymethyl chloride(455331-05-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 455331-05-2(Hazardous Substances Data)

455331-05-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 455331-05-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,5,5,3,3 and 1 respectively; the second part has 2 digits, 0 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 455331-05:
(8*4)+(7*5)+(6*5)+(5*3)+(4*3)+(3*1)+(2*0)+(1*5)=132
132 % 10 = 2
So 455331-05-2 is a valid CAS Registry Number.

455331-05-2Downstream Products

455331-05-2Relevant articles and documents

Lewis acid-activated chiral leaving group: Enantioselective electrophilic addition to prochiral olefins

Nakamura, Hiroko,Ishihara, Kazuaki,Yamamoto, Hisashi

, p. 5124 - 5137 (2002)

A new strategy using a BINOL derivative as a chiral leaving group and Lewis acid has been developed for enantioselective alkylation of prochiral olefins. (R)-2,2′-Bis[2-(trimethylsilyl)ethoxy- methyl]-1,1′-binaphthol is demonstrated to be an effective reagent for enantioselective hydroxymethylation of silyl enol ethers and trisubstituted alkenes. Electrophilic addition to prochiral olefins is accompanied by cleavage of an acetal that is dual activated by SnCl4 and the δ-effect of silicon through the SN2 substitution process. Enantioselective synthesis of cyclic terpenes is also described using this strategy.

METHOD OF PRODUCING SILYLALKOXYMETHYL HALIDE

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Page/Page column 7, (2008/06/13)

A method for making a silylalkoxymethyl halide at good yield represented by the formula: R1R2R3Si-R4-O-CH2X wherein R1, R2, and R3 are an alkyl, cycloalkyl, aryl group, or a halogen atom, R4 is a divalent hydrocarbyl group having 1 to 10 carbon atoms, and X is a halogen atom, by reacting: (a) a silyl alcohol compound with the formula R1R2R3Si-R4-OH wherein R1, R2, R3 and R4 are defined as above, with (b) formaldehyde or a polymer thereof, and (c) a halosilane.

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