4554-22-7Relevant academic research and scientific papers
Can C-H ··· C(π) bonding be classified as hydrogen bonding? A systematic investigation of C-H ··· C(π) bonding to cyclopentadienyl anions
Harder
, p. 1852 - 1861 (2007/10/03)
The following ammonium and phosphonium cyclopentadienide complexes have been prepared, crystallized and investigated structurally: [Cp]-[Et4N]+, [Cp]-[Et4P]+, [Cp]-[Ph3/sub
ORTHO-LITHIATION OF TRIPHENYLPHOSPHINO-METHYLID AND, ALSO, TRIPHENYLPHOSPHINE OXIDE
Schaub, Bruno,Jenny, Titus,Schlosser, Manfred
, p. 4097 - 4100 (2007/10/02)
While upon treatment with methyl- or butyllithium triphenylphosphonio-methylid (1) undergoes extensive ligand exchange (leading to 4) it reacts with sec- or tert-butyllithium mainly at the ortho-position exchanging one hydrogen against a lithium atom (to give 3).
