45648-69-9Relevant academic research and scientific papers
Addition of NOCl to cyclic vinylsilanes: An unexpected reversal of regiochemistry
Mallya, M. Narendra,Nagendrappa, Gopalpur,Shashidhara Prasad,Sridhar,Lokanath,Begum
, p. 2565 - 2568 (2001)
NOCl adds to cyclic vinylsilanes in a syn manner with NO+ bonding to the β-carbon and Cl- to the α-carbon, which is a reversal of the regiochemistry expected from the β-silicon effect. The adducts dimerize to a single diastereomer containing enantiomeric pairs and/or give secondary products on further reaction.
