4584-01-4Relevant academic research and scientific papers
Effect of Medium on the Acidity Constant of Some New Arylazopyrazolopyrimidine Derivatives
Abd-Allah, Elham M.,Rageh, Nasr M.,Salman, Hassan M.A.
, p. 652 - 656 (2007/10/03)
The acid dissociation constants of some new 8-[(aryl)azo]-2,4-dimethylpyrazolo[1,5-a]pyrimidine-7(6H)-one derivatives were determined in aqueous-organic solvent mixtures (methanol, ethanol, acetone, and dimethylformamide (DMF)). Methanol and DMF had approximately similar relative permittivity constants (32.6 and 36.7, respectively, at 25°C), and all the compounds were more acidic in water + DMF than in water-methanol although the same mole fraction of each was used. The increase in the acid dissociation constants (pKa) of the compounds as the proportion of the organic cosolvent in the medium was increased could be ascribed, in addition to the electrostatic effect, to the hydrogen-bonding interaction between the conjugate base (A-) and solvent molecules. The pKa values in the presence of the poorer hydrogen bond donor DMF were less than those obtained in the presence of corresponding amounts of the other solvents.
COORDINATION COMPOUNDS OF HETEROCYCLIC AZO DERIVATIVES II- TRANSITION METAL CHELATES OF SOME PYRAZOLONE AZO DYES
Mahmoud, M. R.,Adam, F. A.,Yousef, K.,El-Haty, M. T.
, p. 13 - 20 (2007/10/02)
The chelates of some 4-arylazo-3-amino-pyrazolone derivatives with Mn(II), Fe(III), Zr(IV), Pd(II) and Ag(I) are prepared and characterized.It is concluded that the ligands and the complexes exist mainly in the hydrazone-keto form.It is confirmed that such compounds are coordinated to the metal ion as monovalent bidentate ligands, L-, and the bonding sites are the oxygen of the carbonyl group and the α-nitrogen of the arylazo group.
