458523-71-2Relevant academic research and scientific papers
Reactivity of electrophilic terminal phosphinidene complexes toward phosphorus ylides
Huy, Ngoc Hoa Tran,Compain, Carine,Ricard, Louis,Mathey, Francois
, p. 57 - 58 (2002)
Stabilised phosphorus ylides react with transient terminal phosphinidene complexes [RP-W(CO)5] (R=Ph, Me) to give products resulting from a formal insertion of P into a C-H bond via an initial nucleophilic attack of the ylidic carbon.
