458566-00-2Relevant academic research and scientific papers
Palladium-catalyzed chloride substitution of η5-(Chlorocyclohexadienyl)Mn(CO)3 complexes: An access to novel η6-(Arene)Mn(CO)3+ cations
Auffrant, Audrey,Prim, Damien,Rose-Munch, Francoise,Rose, Eric,Schouteeten, Stephanie,Vaissermann, Jacqueline
, p. 1898 - 1913 (2008/10/08)
Functionalization of η5-(chlorocyclohexadienyl)Mn(CO)3 complexes was achieved by palladium-catalyzed reactions using Pd2(dba)3 in the presence of AsPh3. Arylation, carbonylation, and substitution by a
Selective access to electron donating group substituted (η5-cyclohexadienyl)Mn(CO)3 complexes by bimetallic manganese-palladium activation
Auffrant, Audrey,Prim, Damien,Rose-Munch, Fran?oise,Rose, Eric,Vaissermann, Jacqueline
, p. 3500 - 3502 (2008/10/08)
Unprecedented (η5-cyclohexadienyl)Mn(CO)3 complexes bearing an electron-donating group at the end of the π system have been selectively prepared using Pd catalysis and primary, secondary cyclic, and acyclic amines. This catalytic met
