458569-45-4Relevant academic research and scientific papers
Synthesis of enantiomerically enriched triarylmethanes by enantiospecific suzuki-miyaura cross-coupling reactions
Matthew, Smitha C.,Glasspoole, Ben W.,Eisenberger, Patrick,Crudden, Cathleen M.
supporting information, p. 5828 - 5831 (2014/05/20)
The Suzuki-Miyaura cross-coupling of chiral, enantiomerically enriched dibenzylic boronic esters is described. The reaction proceeds with almost complete retention of stereochemistry, providing access to triarylmethanes, compounds that have high biologica
Quantitative data on the effects of alkyl substituents and Li-O and Li-N chelation on the stability of secondary a-oxy-organolithium compounds
Monje, Pablo,Grana, Paula,Paleo, M. Rita,Sardina, F. Javier
, p. 2277 - 2289 (2008/02/04)
A ΔGeq stability scale of secondary a-oxy-organolithium compounds was established from measurements of tin-lithium exchange equilibria in THF, and the quantitative effects of substituents at the anionic center on carbanion stability are present
