459-70-1Relevant academic research and scientific papers
REACTIONS OF HALOGEN FLUORIDES. XIII. NEW POSSIBILITIES FOR OXIDATIVE NUCLEOPHILIC FLUORINATION OF BROMINE-SUBSTITUTED ESTERS BY THE HEXACHLOROMELAMINE-HYDROGEN FLUORIDE SYSTEM
Chuvatkin, N. N.,Panteleeva, I. Yu.,Kurskii, Yu. A.,Boguslavskaya, L. S.
, p. 1450 - 1456 (2007/10/02)
Primary, secondary, and tertiary bromine atoms in bromine-substituted esters, including the bromine atoms of the CBr2 group at the α position to the ester group, are substituted effectively by a bromine atom in the hexachloromelamine-liquid hydrogen fluoride system under normal conditions.New methods were developed for the production of alkyl and fluoroalkyl 2,3-dihalogeno-2-fluoropropionates, which are key compounds in the synthesis of α-fluoroacrylates.
