460738-83-4Relevant academic research and scientific papers
Late transition metal complexes derived from diphosphazane monosulfide ligands: X-ray crystal structures of [Ru3(μ-CO)(CO)7-(μ3-S) {Ph2PN((S)-*CHMePh)PPh2- κ2P,P}] and [Rh(CO)Cl{Ph2
Raghuraman, Kannan,Krishnamurthy, Setharampattu S.,Nethaji, Munirathinam
, p. 79 - 86 (2007/10/03)
The oxidative addition reactions of diphosphazane monosulfides, Ph2PN(R)P(S)Ph2 (R=(S)-*CHMePh (1), CHMe2 (2)) with [Ru3(CO)12] afford sulfur-monocapped triruthenium clusters of the type PP
Complexes of elements of groups 9 and 10 with new chiral chelating bisphosphine monosulfide and monoselenide ligands
Faller, Jack W.,Lloret-Fillol, Julio,Parr, Jonathan
, p. 883 - 888 (2007/10/03)
The chiral bisphosphine prepared from the reaction of (S)-α-methylbenzyl amine with two equivalents of chlorodiphenylphosphine can be oxidised by direct reaction with one equivalent of either of the elemental chalcogens sulfur or selenium to prepare new chiral monoxidised bisphosphines. These chiral ligands can be used to prepare complexes with group nine [Rh(I), Ir(I)] and group ten [Pd(II) and Pt(II)] metals. These complexes were characterised by spectroscopic and, in four cases, crystallographic techniques.
Chiral sulfur diphosphazanes derived from S-(Ph2P)2N(CHMePh) and its rhodium(I), (III) and iridium(III) complexes. Crystal structures of Ph2P(S)N(CHMePh)PPh2, {Ph2P(S)}2N(CHMePh) and [(Cp*)
Simón-Manso, Eugenio,Valderrama, Mauricio,Gantzel, Peter,Kubiak, Clifford P.
, p. 90 - 97 (2007/10/03)
The reaction of S-(Ph2 P)2N(CHMePh) with sulfur (1:1 molar ratio) in diethyl ether solution leads to S-Ph2P(S)N(CHMePh)PPh2 (1). The disulphide S-{Ph2P(S)}2N(CHMePh) (2), was obtained when
