460745-18-0

Upstream product

• 206866-61-7 2,3-di-O-acetyl-4,6-O-benzylidene-D-glucopyranosyl trichloroacetimidate 
• 460745-17-9 [(6S)-1-undecen-6-yl] 3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 201542-22-5 (6S)-undec-1-en-6-ol 
• 460745-16-8 [(6S)-1-undecen-6-yl] 2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 108869-64-3 3,4,6-tri-O-benzyl-2-O-acetyl-α-D-glucosyl trichloroimidate 
• 79218-68-1 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucopyranose 
• 65827-55-6 1,2-di-O-acetyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside 
• 53270-12-5 1,2-O-(1-ethoxyethylene) 3,4,6-tri-O-benzyl-1-thio-α-D-glucopyranose 

Downstream Products

• 528603-39-6 (2R,4aR,6S,7R,8R,8aR)-6-[(2R,3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-((S)-1-pentyl-hex-5-enyloxy)-tetrahydro-pyran-3-yloxy]-8-(4-methoxy-benzyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-ol 
• 528603-38-5 (2R,4aR,6S,7R,8S,8aS)-6-[(2R,3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-((S)-1-pentyl-hex-5-enyloxy)-tetrahydro-pyran-3-yloxy]-7-(4-methoxy-benzyloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol 
• 528603-44-3 acetic acid 8-acetoxy-6-{6-[4,5-bis-benzyloxy-6-benzyloxymethyl-2-(1-pentyl-hex-5-enyloxy)-tetrahydro-pyran-3-yloxy]-7-hydroxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy}-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-7-yl ester 
• 460745-19-1 (2R,4aR,6S,7R,8R,8aS)-6-[(2R,3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-2-((S)-1-pentyl-hex-5-enyloxy)-tetrahydro-pyran-3-yloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Relevant academic research and scientific papers

Total synthesis of woodrosin I - Part 1: Preparation of the building blocks and evaluation of the glycosylation strategy

The preparation of three building blocks required for the total synthesis of woodrosin I (1) is outlined, a complex resin glycoside bearing a macrolide ring which spans four of the five sugars of its oligosaccharide backbone. Key steps involve the enantio

Total synthesis of woodrosin I

The reliability of ring-closing metathesis, even in complex cases, is highlighted in the first total synthesis of the structurally intriguing resin glycoside woodrosin I (1). The synthesis also shows the maturity of the trichloroacetimidate method for gly