4608-41-7

Upstream product

• 22460-07-7 (±)-2-(p-tolyl)cyclopentan-1-one 
• 74-88-4 methyl iodide 
• 113344-44-8 2-(4-methyl-2-cyclohexen-1-yl)-2-methylcyclopentanone 
• 1120-72-5 2-Methylcyclopentanone 
• 76430-23-4 2-methylcyclopentanone dimethyl acetal 
• 509323-81-3 dimethyl-[2-(2-methyl-cyclopent-1-enyloxy)-ethyl]-amine 
• 19980-43-9 1-(trimethylsilyloxy)cyclopentene 
• 122346-01-4 2-(4-Methyl-cyclohexa-2,4-dienyl)-cyclopentanone 
• 94853-59-5 ethyl 2-carbethoxy-2-(p-methylbenzyl)-4-formylbutanoate 
• 77037-06-0 2-(4-methylphenyl)-2-cyclopenten-1-one 
• 938-94-3 (R,S)-2-(4'-methylphenyl) propionic acid 
• 174229-36-8 C₁₃H₁₄O 
• 1352812-24-8 2-allyl-2-(p-tolyl)propionic acid 
• 120-92-3 cyclopentanone 

Downstream Products

• 77250-00-1 5-[1-Butylsulfanyl-meth-(E)-ylidene]-2-methyl-2-p-tolyl-cyclopentanone 
• 111768-72-0 Z-2,3-Dimethyl-3-(4-methylphenyl)cyclopentanon 
• 5006-53-1 (+/-)-Epilaurene 
• 77250-01-2 C₂₂H₂₆N₂O₂S 
• 77249-99-1 2,3-Dimethyl-3-p-tolyl-cyclopent-1-enecarbaldehyde 
• 5006-53-1 (+/-)-laurene 
• 111768-71-9 E-2,3-Dimethyl-3-(4-methylphenyl)cyclopentanon 
• 16982-00-6 1-(1,2,2-trimethylcyclopentyl)-4-methylbenzene 
• 54750-40-2 1-(1,2-dimethylcyclopent-2-en-1-yl)-4-methylbenzene 

Relevant academic research and scientific papers

Regioselective silver-mediated Kondakov-Darzens olefin acylation

Enone construction: A silver-mediated olefin acylation reaction is described, in which five-, six-, and -seven-membered rings, tetrasubstituted olefins, bridged bicycles, spirocycles, and benzoxepinones are prepared. Highly selective intermolecular reactions are coupled to a Nazarov cyclization for the effective preparation of cyclopentenones, including the core of modhephene (see scheme). Copyright

A new highly asymmetric chelation-controlled heck arylation

This communication describes the development of a new highly asymmetric chelation-controlled Heck arylation. The methodology permits formation of 2-aryl-2-methyl cyclopentanones in good to very good two-step yields (45-78%) with excellent chiral enrichmen

THE SYNTHESIS VIA ORGANOIRON COMPLEXES OF PEDICELLANIN METHYL ETHER AND CUPARENE

A synthetic route to Pedicellanin methyl ether as well as to Cuparene via iron tricarbonyl-cyclohexadienyl cations is reported.The unusual aromatization reaction of the iron tricarbonyl- cyclohexadienyl mojety by iron trichloride is evidencied.

Use of the Ketal Claisen Rearrangement for the Synthesis of Cyclic Sesquiterpenes Containing Quaternary Centers. A Formal Synthesis of Cuparene.

We have shown that the ketal based Claisen rearrangement can be useful for generating vicinal quaternary and tertiary-quaternary centers by suitable substitution on the reacting 2-cyclohexenols and cycloalkanone ketal.A rapid and efficient method for preparing hindered cycloalkanone ketals in very pure form is presented, as well as a useful modification for synthesizing the requied 2-cyclohexenols from alkyl anisoles with a minimum number of undesired side products.

Synthesis of α-Cuparenone

Ethyl 2-carbethoxy-3-p-tolylpropanoate (VII) on Michael reaction with acrolein followed by acetal formation furnishes acetal-malonate (IX).The diacid (X), obtained by hydrolysis of IX, is warmed with lead tetraacetate-pyridine mixture, and the resulting p

Direct Geminal Dimethylation of Ketones using Dimethyltitanium Dichloride

Ketones are readily converted into the corresponding geminal dimethyl derivatives on reaction with dimethyltitanium dichloride under mild conditions; tertiary alcohols react similarly.