4610-65-5Relevant academic research and scientific papers
REACTION OF NUCLEOPHILES WITH ELECTRON ACCEPTORS BY SN2 OR SINGLE ELECTRON TRANSFER (S.E.T.) MECHANISMS: THIOLATES AND 2-HALOMETHYL-5-NITROFURANS.
Beadle, Charles D.,Bowman, W. Russell,Prousek, Josef
, p. 4979 - 4982 (2007/10/02)
Thiolates react with 2-halomethyl-5-nitrofurans to yield 5-nitrofurfuryl sulphides by a SN2(C) mechanism, and disulphides and 2-methyl-5-nitrofuran by a SN2(X) mechanism.
ELECTRON TRANSFER PROCESSES. REACTION OF 5-NITROFURYL DERIVATIVES GOING BY ANIONRADICAL MECHANISM
Prousek, Josef
, p. 3347 - 3353 (2007/10/02)
5-nitrofurfuryl nitrate and bromide (1a,b) react with electron donors to give 1,2-bis(5-nitro-2-furyl)ethane (II), 1,2-bis(5-nitro-2-furyl)ethylene (III), 5-nitro-2-methylfurane (IV), products of SRN1 reactions Va, Vb and other derivatives.Formation of the derivatives II to V is discussed on the basis of anionradical mechanism. 5-Nitrobenzyl bromide reacts by a SRN1 reaction with 5-nitrofurfuryl phenyl sulphone (Va) in basic medium to give 1-(5-nitro-2-furyl)-1-phenylsulphonyl-2-(4-nitrophenyl)ethane (VIII) and 1-(5-nitro-2-furyl)-2-(4-nitrophenyl)ethylene (IX).
