46125-60-4Relevant academic research and scientific papers
Transmetalation as a Route to Novel Styryllithium Reagents
Rim, Chinwon,Son, David Y.
, p. 3443 - 3445 (2003)
(Equation presented) Transmetalation of β-tributyl(styryl)stannanes with n-BuLi gives the functional equivalents of the corresponding styryllithium intermediates. Reaction of the intermediates with chlorotrimethylsilane, iodomethane, or dimethyl sulfate gives the substituted styryl products in moderate to good yields. In all cases, the configuration about the double bond was retained in the products.
Photoelectron Spectra of Paracyclophane and Paracyclophane-4-ene. An Estimation of Inductive and Hyperconjugative Effect for Paracyclophanes
Gleiter, Rolf,Hopf, Henning,Eckert-Maksic, Mirjana,Noble, Karl-Ludwig
, p. 3401 - 3403 (2007/10/02)
Based on the split of the first two bands in the photoelectron(PE)spectra of paracyclophane, paracyclophane-4-ene, 1,4-di-n-butyl-, 1,4-di-n-propyl- and 1,4-diethylbenzene as well as p-xylene it is shown that the inductive and hyperconjugative effec
