462630-01-9Relevant academic research and scientific papers
Palladium(II) complexes with the mixed-donor ligand CH3S-(CH2)3-PPh2 crystal structures of [PdCl2{CH3S-(CH2)3-PPH 2}n] (n = 1, 2)
Al-Shami, Ehab M.,Abu-Surrah, Adnan S.,Klinga, Martti,Hodali, Hamdallah A.
, p. 1433 - 1436 (2008/10/08)
The phosphorus-sulfur ligand 1-(methylthio)-3-(diphenyl-phosphino)-propane (S-P3) has been synthesized and characterized by 1H NMR and 13C NMR. Reactions of S-P3 with [PdCl2(PhCN)2] afforded the complexes [PdCl2(S-P3)] (I) and [PdCl2(S-P3)2] (II), in which S-P3 acts as a bidentate and monodentate ligand, respectively. Compound I crystallizes in monoclinic space group P21/n (No. 14) with cell dimensions: a = 8.589(3), b = 15.051(3), c = 17.100(3) A, β = 102.91(2)°, V = 2154.7(9) A3, Z = 4. Likewise, compound II crystallizes in monoclinic space group P21/n (No. 14) with a = 9.993(5), b = 8.613(4), c = 18.721(5) A, β = 90.18(3)°, V = 1611.3(12)A3, Z = 2. Compound II has a trans square planar configuration with only the P-site of the ligand bonded to the palladium atom.
