462632-87-7Relevant articles and documents
Stereoselective synthesis of (E)-β-tributylstannyl-α,β-unsaturated ketones: Construction of a key intermediate for the total synthesis of zoanthamine
Nielsen, Thomas E.,Tanner, David
, p. 6366 - 6371 (2002)
(E)-β-Trialkylstannyl-α,β-unsaturated ketones are readily available from secondary propargylic alcohols via a two-step sequence involving highly regio- and stereoselective Pd(0)-catalyzed hydrostannation followed by mild oxidation (TPAP). The methodology
α-fluoroallenoate synthesis via N-heterocyclic carbene-catalyzed fluorination reaction of alkynals
Wang, Xu,Wu, Zijun,Wang, Jian
supporting information, p. 576 - 579 (2016/02/18)
The first catalytic α-fluoroallenoate synthesis is described. With a suitable combination of N-heterocyclic carbene precatalyst, base, and fluorine reagent, the reaction proceeded smoothly to yield a wide range of α-fluoroallenoates with excellent chemose
Dynamic kinetic asymmetric allylic alkylations of allenes
Trost, Barry M.,Fandrick, Daniel R.,Dinh, Diana C.
, p. 14186 - 14187 (2007/10/03)
The dynamic kinetic asymmetric allylic alkylations of racemic allene acetates has been developed with the DACH-phenyl Trost ligand 2 to give general access to allenes with high enantiomeric excess (84-95%) for both malonate and amine nucleophiles. Further
