463298-84-2Relevant academic research and scientific papers
Palladium complexes with bidentate P,N ligands: Synthesis, characterization and application in ethene oligomerization
Müller, Gabi,Klinga, Martti,Osswald, Peter,Leskel?, Markku,Rieger, Bernhard
, p. 803 - 809 (2002)
Palladium complexes of two different P,N ligands (a phosphane-pyridine and a phosphane-imine ligand) were synthesized and characterized. Single crystal X-ray structure analyses of the palladium diiodide compounds revealed a square-planar coordination geometry at the metal center with a longer Pd-I bond in trans-position to the phosphorus atom. The chloro-methyl palladium species of the phosphane-pyridine ligand was applied for the oligomerization of ethene using a borate salt as cocatalyst.
