46373-45-9Relevant articles and documents
Remarkable cage deboronation and rearrangement of a closo-1,12- dicarbadodecaborane to form a neutral nido-7,9-dicarbaundecaborane
Ioppolo, Joseph A.,Bhadbhade, Mohan,Fox, Mark A.,Rendina, Louis M.
supporting information, p. 3312 - 3314 (2013/06/27)
Deboronation and cage rearrangement of the closo-1,12-carborane salt [1,12-(PPh2Me)2-1,12-C2B10H 10]I2 occurs in refluxing methanol to give the zwitterionic nido-7,9-carborane 7,9-(PPh2Me)2-7,9-C 2B9H9. Notably, deboronation and cage substitution of the isomeric closo-1,7-carborane salt [1,7-(PPh 2Me)2-1,7-C2B10H10]I 2 takes place in methanol to afford the salt [10-OMe-7,9-(PPh 2Me)2-7,9-C2B9H9]I. The Royal Society of Chemistry 2013.