463935-90-2

Upstream product

• 100-51-6 benzyl alcohol 
• 14125-78-1 2,3,4,6-tetra-O-acetyl-1,5-anhydro-D-lyxo-hex-1-enitol 

Downstream Products

• 463935-93-5 benzyl 6-O-acetyl-3-deoxy-4-S-benzyl-4-thio-α-D-threo-hexopyranosid-2-ulose 
• 463935-92-4 benzyl 6-O-acetyl-3-deoxy-4-S-(2-propyl)-4-thio-α-D-threo-hexopyranosid-2-ulose 
• 463935-99-1 benzyl 6-O-acetyl-3-deoxy-4-S-benzyl-4-thio-α-D-xylo-hexopyranoside 
• 463936-00-7 benzyl 6-O-acetyl-3-deoxy-4-S-benzyl-4-thio-α-D-lyxo-hexopyranoside 
• 463935-97-9 benzyl 6-O-acetyl-3-deoxy-4-S-(2-propyl)-4-thio-α-D-xylo-hexopyranoside 
• 463935-98-0 benzyl 6-O-acetyl-3-deoxy-4-S-(2-propyl)-4-thio-α-D-lyxo-hexopyranoside 

Relevant academic research and scientific papers

Michael addition of thiols to sugar enones. Synthesis of 3-deoxy-4-thiohexopyranosid-2-uloses as key precursors of 3-deoxy- and C-2 branched-chain 4-thiosugars

Benzyl and 2-propyl 6-O-acetyl-3,4-dideoxy-α-D-glycero-hex-3-enopyranosid-2-uloses (2) and (3) were readily prepared by the tin(IV) chloride-promoted glycosylation of glycal (1). The enone system of (2) and (3) underwent a highly diastereoselective Michae