46407-94-7Relevant academic research and scientific papers
Enhanced asymmetric induction in cycloadditions to bridgehead-chiral vinyl dioxazaborocines
Davies, Christopher D.,Marsden, Stephen P.,Stokes, Elaine S.E.
, p. 4229 - 4233 (2000)
Vinyl dioxazaborocines 5 with asymmetric centres on the nitrogen bridgehead substituent have been prepared and assayed in nitrile oxide and nitrone cycloadditions, giving asymmetric inductions of up to 70 and 74% ee, respectively. (C) 2000 Elsevier Science Ltd.
ASYMMETRIC REDUCTION OF KETONES USING LiAlH4 MODIFIED WITH CHIRAL 1,2-AMINODIOLS
Morrison, James D.,Grandbois, Edward R.,Howard, Sachiko I.,Weisman, Gary R.
, p. 2619 - 2622 (2007/10/02)
Four chiral aminodiols from ring opening of (S)-propylene oxide and ethylene oxide with n-butylamine and (R) or (S)-α-methylbenzylamine were used to modify LiAlH4.Asymmetric reduction of acetophenone and propiophenone gave the highest percent enantiomeric
