464169-74-2Relevant academic research and scientific papers
Palladium-Catalyzed Oxidative Silylation of Simple Olefins To Give Allylsilanes Using Hexamethyldisilane and Molecular Oxygen as the Sole Oxidant
Nakai, Syunji,Matsui, Masaki,Shimizu, Yosuke,Adachi, Yurina,Obora, Yasushi
, p. 7317 - 7320 (2015)
A Pd-catalyzed oxidative silylation of simple olefins with hexamethyldisilane to give allylsilanes has been achieved using molecular oxygen as the sole oxidant. The reaction provides a useful protocol to access synthetically useful allylsilanes from easil
A convenient synthesis of z-allylsilanes with good stereoselectivity promoted by samarium diiodide
Concellón, José M.,Rodríguez-Solla, Humberto,Simal, Carmen,Gómez, Cecilia
, p. 75 - 78 (2008/03/27)
Synthesis of Z-allylsilanes in high or good yields and with good stereoselectivity is achieved from O-acetylated 1-silyl-3-chloro alcohols promoted by SmI2. The starting compounds were easily prepared from 2-chloroaldehydes and a mechanism is p
TRIS(2-METHYLPHENYL)PHOSPHORANE, A MODIFIED SEYFERTH-WITTIG REAGENT FOR THE STEREOSELECTIVE SYNTHESES OF Z-ALLYLTRIMETHYLSILANES
Iio, Hideo,Ishii, Masahiro,Tsukamoto, Masamitsu,Tokoroyama, Takashi
, p. 5965 - 5968 (2007/10/02)
The Wittig reactions between title β-silylphosphorus ylide and aliphatic aldehydes give selectively Z-allyltrimethylsilanes with minimal formation of vinylation products.
