4654-18-6Relevant academic research and scientific papers
Preparation method of room-temperature phosphorescent benzoate compound
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Paragraph 0117-0120, (2019/07/16)
The invention relates to a room-temperature phosphorescent benzoate compound. The benzoate compound is prepared by an efficient one-step method, and the prepared benzoate compound has obvious phosphorescence at room temperature, thereby broadening the application range of the benzoate compound. The product can be widely applied to phosphorescent materials.
Synthesis of perfluoroalkyl gelators and their selective gelation ability for fluorinated solvents1
Shimasaki, Toshiaki,Ohno, Yuki,Tanaka, Mao,Amano, Masato,Sasaki, Yuta,Shibata, Hirobumi,Watanabe, Motonori,Teramoto, Naozumi,Shibata, Mitsuhiro
, p. 97 - 104 (2019/01/28)
Novel perfluoroalkyl gelators without hydrogen bondsbis(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) iso-phthalate (1m), bis(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadeca-fluorooctyl) terephthalate (1p), and tris-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-pentadecafluorooctyl) benzene-1,3,5-tricarboxylate (2)were synthesized. Their molecular structures were investigated by density functional theory calculations at the B3LYP/cc-pVDZ level. The gelation abilities of 1m, 1p, and 2 were examined and compared to their normal octyl homologues 1m¤, 1p¤, and 2¤. None of the gelators could be gelated in common organic solvents, but gelated well in fluorinated solvents.
Mucor miehei lipase catalyzed transesterifications on aromatic and heteroaromatic substrates. A general survey
Martin-Munoz, Maria Gema,Fierros, Maria,Rodriguez-Franco, Maria Isabel,Conde, Santiago
, p. 6999 - 7008 (2007/10/02)
An investigation on Mucor miehei lipase-catalyzed transesterifications of 16 aromatic and heteroaromatic esters in organic solvents is described. The points studied were the activity and regioselectivity of the enzyme-catalyzed reaction of either one or two ester groups situated in different positions on several heterocyclic systems with an aliphatic alcohol. The reactions took place in moderate to good yields and, in some cases, regioselectively.
