465512-61-2Relevant academic research and scientific papers
Aryl Fluoroalkyl Sulfoxides: Optical Stability and pKa Measurement
Messara, Amélia,Vanthuyne, Nicolas,Diter, Patrick,Elhabiri, Mourad,Panossian, Armen,Hanquet, Gilles,Magnier, Emmanuel,Leroux, Frédéric R.
, p. 5019 - 5026 (2021/08/13)
The enantiomeric separation of aryl trifluoromethyl and difluoromethyl sulfoxides was realized via chiral chromatography. The configurational stability of each set of enantiomers was then studied by thermal enantiomerization. The ΔG≠ values obt
Efficient asymmetric synthesis of aryl difluoromethyl sulfoxides and their use to access enantiopure α-difluoromethyl alcohols
Batisse, Chloé,Céspedes Dávila, Maria F.,Castello, Marco,Messara, Amélia,Vivet, Bertrand,Marciniak, Gilbert,Panossian, Armen,Hanquet, Gilles,Leroux, Frédéric R.
, p. 3063 - 3079 (2019/05/07)
The -CHF2 moiety has shown a growing interest in pharmaceutical and agrochemical applications over the last few years. Its introduction is therefore a current research topic for organic chemists. Several groups have reported the synthesis of di
Synthesis and optical activity of difluoro(organylsulfinyl)acetic acids and their esters
Matsnev, Andrej V.,Kondratenko, Nataliya V.,Yagupolskii, Yurii L.,Yagupolskii, Lev M.
, p. 2949 - 2952 (2007/10/03)
Representatives of a new type of optically active sulfur(IV) compound, arylsulfinyldifluoroacetic acids, have been prepared.
