466680-03-5Relevant academic research and scientific papers
Cluster Chemistry. XCV. Some More Chemistry of Ru3(μ-dppm)(CO)10: Reactions with Allyl Bromide, Dimethyl Disulfide and AuCl(PPh3), and Preparation of Some Complexes Containing Tertiary Phosphines and Phosphites. X-Ray Structure of Ru3(μ-H)(μ-SMe)(μ-dppm)(CO)8
Bruce, Michael I.,Humphrey, Paul A.,Surynt, Richard J.,Tiekink, Edward R. T.
, p. 477 - 486 (2007/10/02)
Reactions between Ru3(μ-dppm)(CO)10 and several reagents have been studied.With allyl bromide, cluster breakup occurs to give binuclear Ru2(μ-Br)(μ-C3H5)(μ-dppm)(CO)4.With Me2S2, binuclear Ru2(μ-SMe)2(μ-dppm)(CO)4 and trinuclear Ru3(μ-H)(μ-SMe)(μ-dppm)(CO)8 are obtained; the X-ray structure of the latter has been determined.With AuCl(PPh3), addition to one Ru-Ru bond gives AuRu3(μ-Cl)(μ-dppm)(CO)8(PPh3).Some data on tertiary phosphine substituted products formed in reactions with PMe3, PPh3, P(C6H4Me-3)3, P(C6H4Me-4)3, P(OMe)3, P(OCH2CF3)3, dppe and Fe(η-C5H4PPh2)2 are also given.
THE REACTIONS OF FREE AND SURFACE ANCHORED PHOSPHINES WITH MULTIDENTATE LIGAND STABILISED METAL CARBONYL CLUSTER COMPLEXES
Foster, Douglas F.,Harrison, Jane,Nicholls, Barry S.,Smith, Anthony K.
, p. 99 - 108 (2007/10/02)
The trinuclear, bidentate-phosphine stabilised cluster complexes, M3(CO)10(dppm) undergo selective substitution by monodentate phosphines, L, to give M3(CO)9(dppm)L in which
