466692-95-5Relevant academic research and scientific papers
(4-Nitrophenylsulfanylmethyl)triphenylstannane and (4-nitrophenylsulfonylmethyl)triphenylstannane: R22(X) rings (X is 10, 18 or 24) and C-H...π interactions
Skakle, Janet M.S.,Wardell, James L.,Wardell, Colange M.S.V.
, p. m413-m417 (2007/10/03)
In the crystal structures of (4-nitrophenylsulfanylmethyl)triphenylstannane, [Sn(C6H5)3(C7H6 NO2S)]. (I), and (4-nitrophenylsulfonylmethyl)triphenylstannane. [Sn(C6H5)3(C7H6 NO4S)], (II), the molecules are linked by paired C-H...O hydrogen bonds into centrosymmetric dimers which combine to form sheets. In (I), two such dimers form to give R22(10) and R22(24) rings. In (II), similar dimers form, here with R22(10) and R22(18) rings, but with an additional dimer due to the presence of the sulfone group, giving R22(10) rings. In both structures, C-H...π interactions lead to a doubling of the width of the sheets.
