467214-92-2

Upstream product

• 91202-71-0 (Z)-4-bromo-1-(tert-butyldimethylsilyloxy)but-2-ene 
• 467214-80-8 3-((R)-2-Hydroxy-1-phenyl-ethylamino)-cyclohex-2-enone 
• 504-02-9 1,3-cylohexanedione 
• 56613-80-0 D-2-phenylglycinol 

Downstream Products

• 467214-82-0 (E)-4-[(R)-2-(3-Oxo-cyclohex-1-enylamino)-2-phenyl-ethoxy]-but-2-enal 
• 467214-84-2 (4R,10aR)-4-Phenyl-9-piperidin-1-yl-3,4,5,6,7,9,10,10a-octahydro-1H-2-oxa-4a-aza-phenanthren-8-one 
• 467214-81-9 3-[(R)-2-((Z)-4-Hydroxy-but-2-enyloxy)-1-phenyl-ethylamino]-cyclohex-2-enone 

Relevant academic research and scientific papers

Stereoselective formal [3 + 3] cycloaddition approach to cis-1-azadecalins and synthesis of (-)-4a,8a-diepi-pumiliotoxin C. Evidence for the first highly stereoselective 6π-electron electrocyclic ring closures of 1-azatrienes

Evidence is described here to support that a highly stereoselective 6π-electron electrocyclic ring closure of 1-azatrienes is a key step in formal [3 + 3] cycloaddition or annulation reactions of chiral vinylogous amides with α,β-unsaturated iminium salts