467227-79-8

Upstream product

• 302840-42-2 (+)-methyl (1R)-1,5,5-trimethyl-6-methylenecyclohexan-2-one-1-acetate 
• 374782-82-8 ((R)-1,3,3-Trimethyl-2-methylene-cyclohexyl)-acetic acid 
• 374782-79-3 (-)-methyl (1R)-1,3,3-trimethyl-2-methylenecyclohexane-1-acetate 
• 467227-88-9 2-[(1R)-1,3,3-trimethyl-2-methylenecyclohexyl]-ethanol 

Downstream Products

• 467227-80-1 ethyl 2-diazo-4-[(1R)-1,3,3-trimethyl-2-methylene-cyclohexyl]-3-oxobutanoate 
• 467227-78-7 ethyl 4-[(1R)-1,3,3-trimethyl-2-methylenecyclohexyl]-3-oxobutanoate 

Relevant academic research and scientific papers

Enantiospecific total synthesis of ent-10,1 l-thapsan-10-ol

First enantiospecific total synthesis of optical antipode of the sesquiterpene 10,1 l-epoxythapsan-10-ol has been described. (R)-Carvone has been employed as the chiral starting material and a combination of intramolecular alkylation and Criegee fragmenta

The first enantiospecific synthesis of (+)-10,11-epoxythapsan-10-ol: Revision of the absolute stereochemistry of thapsanes

The first enantiospecific synthesis of (+)-cis,anti,cis-1,8,12,12-tetramethyl-4-oxatricyclo[6.4.0.02,6] dodecan-3-ol (+)-1g, an enantiomer of natural thapsane isolated from Thapsia villosa var minor, is accomplished starting from (R)-carvone, w