467242-39-3

Upstream product

• 30889-20-4 methyl cyclohexa-2,5-diene-1-carboxylate 
• 467242-35-9 tert-butyl-{[(2R)-2-(2-iodoethyl)-2-methylcyclopentyl]oxy}dimethylsilane 
• 7424-82-0 methyl (1R)-3-(1-methyl-2-oxocyclopentyl)propanoate 
• 467242-38-2 3-[2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-cyclopentyl]-propionic acid 
• 467242-37-1 3-[2-(tert-butyl-dimethyl-silanyloxy)-1-methyl-cyclopentyl]-propionic acid methyl ester 
• 467242-49-5 3-((R)-2-Hydroxy-1-methyl-cyclopentyl)-propionic acid methyl ester 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 918813-45-3 methyl (1R)-3-(1-methyl-2-oxocyclopentyl)propanoate 
• 918813-49-7 2-(2-iodo-ethyl)-2-methyl-cyclopentanol 
• 918813-46-4 (2R)-2-(2-iodoethyl)-2-methylcyclopentanone 

Downstream Products

• 467242-36-0 methyl (1R)-1-[2-(1-methyl-2-{[(trifluoromethyl)sulfonyl]oxy}cyclopent-2-en-1-yl)ethyl]cyclohexa-2,5-diene-1-carboxylate 
• 467242-40-6 methyl (1R)-1-[2-(1-methyl-2-oxocyclopentyl)ethyl]cyclohexa-2,5-diene-1-carboxylate 
• 467242-51-9 methyl (2R)-1-[2-(2-hydroxy-1-methylcyclopentyl)-ethyl]cyclohexa-2,5-diene-1-carboxylate 

Relevant academic research and scientific papers

Synthetic studies on cyathin terpenoids: Enantioselective synthesis of the tricyclic core of cyathin through intramolecular Heck cyclisation

An enantioselective synthesis of the tricyclic ketone (+)-5, which displays the carbon core of NGF-inducing cyathane diterpenes, has been completed according to a strategy in which the key step was the intramolecular Heck reaction of the AC subunit 49 est

Synthetic studies toward cyathin diterpenoids: Approach to the tricyclic system through intramolecular Heck-type cyclization

The enantioselective synthesis of a model of the core ring system of cyathin diterpenes is described. The key tricyclic acetate 4 was assembled via an intramolecular Heck-type cyclization of the chiral triflate 8. Acetate 4 was taken through to model cyat