468095-29-6

Basic information

• Product Name: Pyrrolidine, 2,3,3-trimethyl-5-(1-methylethyl)- (9CI)
• Synonyms: Pyrrolidine, 2,3,3-trimethyl-5-(1-methylethyl)- (9CI)
• CAS NO: 468095-29-6
• Molecular Formula: C₁₀H₂₁N
• Molecular Weight: 155.28044
• Product Categories: ISOPROPYL
• Mol File: 468095-29-6.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Pyrrolidine, 2,3,3-trimethyl-5-(1-methylethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Pyrrolidine, 2,3,3-trimethyl-5-(1-methylethyl)- (9CI)(468095-29-6)
• EPA Substance Registry System: Pyrrolidine, 2,3,3-trimethyl-5-(1-methylethyl)- (9CI)(468095-29-6)

Safety Data

• Hazardous Substances Data: 468095-29-6(Hazardous Substances Data)

Upstream product

• 81250-41-1 3,3,6-trimethylhepta-4,5-dien-2-one 
• 338465-84-2 methyl 2-(1,2,2,5-tetramethyl-3,4-hexadienylidene)-1-methylhydrazinecarbodithioate 

Relevant articles and documents

Stereoselective reduction and reductive dephosphonylation of β-iminophosphonates

Proline-like 2,4-dialkyl-5-phosphonylpyrrolidines 2 were obtained stereoselectively by reduction of the corresponding β-iminophosphonates 1 with NaBH4. The detailed characterization of compounds 2 was accomplished by 1H and 13C NMR as well as by crystal structure analysis. When 1 was reduced with LiAlH4 the reaction gave dephosphonylated pyrrolidines 3. The latter method is suitable for providing substituted pyrrolidines regioselectively. A possible mechanism for the dephosphonylation is proposed.